Monday, March 12, 2012
An inspirational chemist is inspired by chemistry
CNR Rao has published an auto-biography Climbing the Limitless Ladder: A Life in Chemistry. There are nice reviews in the Hindu newspaper and Chemistry World. It is impressive how he continues to be so passionate about doing science, in spite of many successes and the burden of significant administrative and advising responsibilities.
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The two-state model for spin crossover in organometallics
Previously, I discussed how spin-crossover is a misnomer for organometallic compounds and proposed that an effective Hamiltonian to describe...

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Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro...
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Nitrogen fluoride (NF) seems like a very simple molecule and you would think it would very well understood, particularly as it is small enou...
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I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
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