The use of Empirical Valence Bond methods to describe chemical reactions in complex environments (e.g. solvents and proteins) was pioneered by Warshel. I found the useful table below in a Comment by Jan Florian, arguing that some "new" methods with new acronyms are actually misnomers. [Aside: this is the same issue as The Best Paper Title and Abstract Ever].
Table 1:
Taxonomy of the EVB and Earlier Methodsa
year | 1954 | 1980 | 1991 | 1996 | 1997 | 1998 | 2001 |
acronym | VBb | EVB | EVB | AVB | extended | MS-EVB | MC-MM |
principal | Coulson1 | Warshel2-6 | Miller12 | McCammon11,19 | Borgis15 | Voth14 | Truhlar10,13 |
no. | 3 | 2−8 | 2 | 2−8 | 6−10 | 2 | |
Hiic | Morse | Morse | Morse+MM | Morse+MM | Morse+MM | Morse+MM | MM |
Hijc | exp | const | exp | const | exp | general | general |
analytical | no | yes | no | yes | yes | yes | yes |
solvente | no | in | no | in | in | in | no |
studied | H | enzyme | double-well potentials | phospholipase catalysis | hydrated | hydrated | H |
syst | 3 | 2 | n/a | 2 | 3−13 |
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