In tomorrow's lecture I will talk about immiscible liquids. This shows the importance of entropy of mixing. The temperature-composition phase diagram of two partially immiscible liquids has a critical point. There is a nice video of the critical opalescence associated with the critical point for the cyclohexane-methanol mixture. An Excel spreadsheet for the thermodynamic data is here.
The simple analytical formula for mixing of a regular solution shows how the competition between energy and entropy which drives phase transitions.
Subscribe to:
Post Comments (Atom)
Pattern formation and emergence
Patterns in space and/or time form in fluid dynamics (Rayleigh-Bénard convection and Taylor-Couette flow), laser physics, materials science ...

-
Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro...
-
I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
-
Nitrogen fluoride (NF) seems like a very simple molecule and you would think it would very well understood, particularly as it is small enou...
My father got very worried when I explained to him that the orientability of a cellular surface - on which our existence as thinking salt-water bags relies - was due to no stronger interaction than the separation of salad dressing.
ReplyDelete-seth