The Journal of Chemical Physics website has a fascinating podcast with Roald Hoffmann, Neil Ashcroft, and Vanessa Labet talking about a series of 4 papers they have just published about "molecular" hydrogen under pressure. They illustrate some very rich and subtle physics and chemistry.
It highlights the importance of both physical and chemical insight, simple models, and how there are still these old problems waiting to be solved.
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The two-state model for spin crossover in organometallics
Previously, I discussed how spin-crossover is a misnomer for organometallic compounds and proposed that an effective Hamiltonian to describe...

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Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro...
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Nitrogen fluoride (NF) seems like a very simple molecule and you would think it would very well understood, particularly as it is small enou...
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I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
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