• Electronic correlations can significantly modify the relative energy of excited electronic states, especially near transition states.
• Due to conical intersections between potential energy surfaces non-adiabatic processes can lead to ultrafast internal conversion (transitions between different electronic states).
• The environment has a significant effect on the rate of transitions between quantum states.
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Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro... -
I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
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Nitrogen fluoride (NF) seems like a very simple molecule and you would think it would very well understood, particularly as it is small enou...
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