As mentioned in a previous post organic charge transfer salts have revealed rich new physics associated with strong electronic correlations. The family kappa-(BEDT-TTF)2X has the phase diagram below as a function of temperature and pressure. There is a first-order phase transition between a Mott insulator and a metal (which becomes superconducting below about 12 K. The first-order transition line ends a critical point at about 40 K.
In 2005, Kagawa, Kawamoto, and Kanoda published a beautiful paper in Nature which did a scaling analysis of the conductivity near the critical point. From the figure below they could the extract critical exponents show (delta,beta,gamma)=(2,1,1). These values did not
correspond to any known universality class. This is in distinct contrast to the critical exponents found for the corresponding metal-insulator transition for vanadium sesquioxide (V2O3) doped with chromium. In that case the exponents were those for the three dimensional Ising transition (liquid-gas transition).
Subsequently, Imada investigated theoretically how this universality class could emerge due to a marginal quantum critical region near a Mott transition. Misawa and Imada found how this class corresponded to the marginal point between the Ising transition and the topological transition of the Fermi surface.
I remember someone telling me there were problems with this theory
and so hopefully someone can write a comment about that.
So another example how the organic charge transfer salts are a
playground for emergent phenomena arising from quantum many-body physics.
Subscribe to:
Post Comments (Atom)
Emergence and protein folding
Proteins are a distinct state of matter. Globular proteins are tightly packed with a density comparable to a crystal but without the spatia...
-
Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro...
-
If you look on the arXiv and in Nature journals there is a continuing stream of people claiming to observe superconductivity in some new mat...
-
I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
No comments:
Post a Comment