On my previous post on the 20 key concepts, Will Polik wrote a helpul comment:
Related to concept 10 (free energy), I think that a key concept in the practical application of thermodynamics is the idea that "the entropy of the universe tends toward a maximum" is equivalent to "the Gibbs free energy of the system (at constant T and P) tends toward a minimum" and the corresponding statement about Helmholtz free energy. This allows one to use just the state properties of the system to determine the direction of change and equilibrium conditions, rather than having to worry about the entire universe!
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