Monday, September 12, 2011

How bad can a metal get?

A striking feature of strongly correlated electron materials is the existence of bad metallic behaviour. The resistivity can monotonically increase with temperature to values which are much larger than the Mott-Ioffe-Regel limit, a value corresponding (in a simple Drude model) to a value where the mean-free path is smaller than a lattice constant.
Key questions are
  • Does the resistivity ever "saturate" at high temperatures?
  • If so, to what value is the maximum possible resistivity?
  • Could this be related to the large spectral weight spread out over a broad spectral range in the optical conductivity? (see the next figure below).
There is a nice summary of the issues in section VIIH of this RMP by Basov and Timusk.

Gunnarsson and collaborators have come up with a simple argument to address these questions [see this nice RMP colloquium].

At high enough temperatures there is no Drude peak in the optical conductivity. However, the latter must still satisfy the f-sum rule, which relates the total "low energy" spectral weight to the average kinetic energy, E_K. The spectral weight may be spread over the non-interacting band width W.
These observations can be summarised in the figure and equation below which provides an estimate for the dc conductivity  sigma(0) on the scale e^2/(h d) where d is the interlayer spacing.
A recent PRB by Bergeron, Hankevych, Kyung, and Tremblay calculates the optical conductivity for the Hubbard model at the level of a two-particle self-consistent approach, including the constraint of the f-sum rule. The curves below is for a doping p=0.2 , close to optimal,  and a temperature of T=0.2t.
Qualitatively, it seems consistent with the predictions of Gunnarsson et al.

No comments:

Post a Comment

Elastic interactions and complex patterns in binary systems

One of the many beauties of condensed matter physics is that it can reveal and illuminate how two systems or phenomena that at first appear ...