There is a good Opinion piece in the November Scientific American, Fudge Factor: a look at Harvard science fraud case by Scott O. Lillienfeld. He discusses the problem of distinguishing intentional scientific fraud from confirmation bias, the tendency we have as scientists to selectively interpret data in order to confirm our own theories.
This is a good reminder that the easiest person to fool is yourself.
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The two-state model for spin crossover in organometallics
Previously, I discussed how spin-crossover is a misnomer for organometallic compounds and proposed that an effective Hamiltonian to describe...

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Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro...
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Nitrogen fluoride (NF) seems like a very simple molecule and you would think it would very well understood, particularly as it is small enou...
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I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
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