Magnetite (Fe3O4) has the AM2X4 spinel structure, of the "inverse" type :
Magnetite has the empirical formula Fe3O4, or Fe2+(Fe3+O2)2, “ferrous ferrite”. Its formula as a spinel would be Fe3+tetFe2+octFe3+octO4 , where "tet" and "oct" stand for tetrahedral and octahedral coordinations by the oxide anions. In the above model, the blue spheres represent the tetrahedral iron(III) cations , and the red spheres are the octahedrally coordinated iron(II) and (III) cations. The oxide anions are shown as the green spheres. Because of the fortuitous inverse nature of the magnetite structure, ferrous and ferric cations are both in the similar octahedral coordination by oxides. In "normal" spinels, such as the mineral spinel itself (magnesium aluminate), the A cation is tetrahedral and the M cations are both octahedral:
The charge order situation in magnetite is a rich, complicated problem with a 70+ year history. See here for a recent take on what is going on, particularly with reference to the Verwey transition and the ground state:
ReplyDeletehttp://prb.aps.org/abstract/PRB/v76/i16/e165124