Tuesday, September 29, 2009
Give and take in organometallic complexes
Following up on my previous post on pi-back-bonding in organometallic complexes I came across this nice paper which considers a complex which has such strong interaction between the LUMO on the organic ligand and one of the d-orbitals on the metal (actually the metal plus some other ligands) that the bond is almost covalent.
Above I reproduce the nice figure from the online abstract since it summarises the paper so nicely and unfortunately is not in the paper.
Subscribe to:
Post Comments (Atom)
A very effective Hamiltonian in nuclear physics
Atomic nuclei are complex quantum many-body systems. Effective theories have helped provide a better understanding of them. The best-known a...
-
Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro...
-
If you look on the arXiv and in Nature journals there is a continuing stream of people claiming to observe superconductivity in some new mat...
-
I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
No comments:
Post a Comment