In the first part I try to show the best logical structure of thermodynamics is to actually start with the Second law. This was something I was introduced to as an undergraduate by Hans Buchdahl (who later became my honours supervisor). His ideas are contained in his The Concepts of Classical Thermodynamics. Similar ideas are now championed by Elliot Lieb and Jacob Yngvason, and described in this nice Physics Today article.
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Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro... -
Nitrogen fluoride (NF) seems like a very simple molecule and you would think it would very well understood, particularly as it is small enou... -
I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
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