Tuesday, March 11, 2025

Topological defects determine the strength and growth rate of crystals

 The quantum theory of solids developed in the 1920s provided a theoretical estimate of the ideal strength of crystals. The problem was that this estimate was a thousand times greater than the measured strength of metals. This paradox was resolved in 1934, when Egon Orowan, Michael Polanyi and G. I. Taylor, independently proposed that plastic deformation could be explained in terms of the theory of dislocations. Aside: this is an example of how macroscopic properties can be determined by structures at the mesoscale rather than microscopic properties.

By 1940 the accepted theory of crystal growth was that it occurred by nucleation of successive close-packed layers of the crystal and this provided algebraic expressions for growth rates that were consistent with experiment. However, around 1950 Keith Burton estimated the parameters in the theory and pointed out that it predicted a growth rate that was smaller than observed growth rates by a factor 10^1000, i.e., 1000 orders of magnitude!

This quantitative discrepancy was resolved by Burton, Nicolas Cabrera and Charles Frank in 1951 who showed the central role played by screw dislocations. A crystal does not grow by the independent nucleation of separate layers. Rather it grows from just one layer that heloicoidally overlapping itself. A signature of this growth mode is the presence of spiral steps on crystal surfaces and they were subsequently observed.

This history is beautifully recounted in the introduction to a review article on Snow Crystals published by Charles Frank in 1982. It was reprinted in 2009 with an introduction by Andrew Fisher.

Following the introduction Frank discusses how snow is an important example of crystal growth that is not attributable to the presence of screw dislocations.

In 2015, D.P. Woodruff wrote a commentary on the classic 1951 paper by Burton, Cabrera, and Frank.

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Topological defects determine the strength and growth rate of crystals

 The quantum theory of solids developed in the 1920s provided a theoretical estimate of the ideal strength of crystals. The problem was that...