Sunday, January 2, 2011
Tuning electronic dimensionality with chemistry
An interesting Chemistry of Materials paper illustrates how different types of stacking of organic molecules leads to electronic structures with different dimensionality. This is important in the quest to find Mott insulators with frustrated interactions that are tuned to produce a spin liquid ground state. However, it looks like these materials cannot be described by a half-filled band (there is only a small dimerisation) but rather should be described by a three-quarters filled band.
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Lamenting the destruction of science in the USA
I continue to follow the situation in the USA concerning the future of science with concern. Here are some of the articles I found most info...

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Is it something to do with breakdown of the Born-Oppenheimer approximation? In molecular spectroscopy you occasionally hear this term thro...
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I welcome discussion on this point. I don't think it is as sensitive or as important a topic as the author order on papers. With rega...
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Nitrogen fluoride (NF) seems like a very simple molecule and you would think it would very well understood, particularly as it is small enou...
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